Amber Stanley, 24, and her two children Jack (4) and Autumn (2) from Callahan, Florida, all died as a result of the crash.
The State Patrol said Elias Kipkosgei, 25, of Marshall, received non life-threatening injuries in the crash and was taken to Avera Marshall Regional Medical Center.
An Antioch man had to be extricated from his auto after it overturned off Highway 101 in Paso Robles on Monday morning, the California Highway Patrol said.
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The accident occurred at 12:49 a.m.as Staley's 2011 Kia Soul was traveling north on the interstate, according to S.C. Highway Patrol Lance Cpl. The vehicle then ran off the road, hit a tree and caught fire, officials say.
The crash remains under investigation and charges are pending against the driver, troopers said.