The Australian Open champion went out before the third round for the fourth time in seven years, losing 6-4, 1-6, 7-5 to Ekaterina Makarova of Russian Federation after complaining to the chair umpire about the insects that invaded No. 1 court during the second set.
"I think it just shows the depth of women's tennis right now", the 23-year-old Keys told reporters. Not wasting too much energy in the first matches is nice to have.
No such problems for Federer, who won 35 straight points on his serve on route to beating Lukas Lacko of Slovakia 6-4, 6-4, 6-1.
Venus reached her ninth Wimbledon final a year ago, but the American star was denied a sixth title by Garbine Muguruza. "I was fortunate to get through that tiebreaker on two well-played points". She produced her best tennis to save three match points when 5-3 and 40-0 behind, and saved another before breaking to level the set.
The Swiss defending champion has now won 26 consecutive sets at the All England Club.
"On certain days it goes better than others", Federer said.
Raonic had just four break-point opportunities in the match, winning one.
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"I played very well". "I'm happy how I am hitting the ball, good concentration on my service games and able to mix it up with some slices".
Raonic avoided a confrontation with a seeded player in the third round as qualifier Dennis Novak of Austria upset No. 17 Lucas Paille of France 6-4, 6-2, 6-7 (8), 3-6, 6-2 on Wednesday. Riske and Savchuk lead 7-6 (5), 2-6, 3-2 in a match scheduled to conclude on Thursday.
"It was better than the first round".
Seven-times champion Serena Williams moved up a gear at Wimbledon to beat Bulgarian qualifier Viktoriya Tomova 6-1 6-4 on Wednesday and reach the third round.
Former world number one Karolina Pliskova finally made it to the third round on her seventh visit to Wimbledon after seeing off two-time Australian Open champion Victoria Azarenka 6-3, 6-3.
Keys, the runner-up to close friend Sloane Stephens at the US Open last year, made the quarter-finals at Wimbledon in 2015 but was knocked out in the second round last year by Simona Halep.